Iron-Catalyzed Silylation of Alcohols by Transfer Hydrosilylation with Silyl Formates

Timothé Godou 1 Clément Chauvier 1 Pierre Thuéry 1 Thibault Cantat 1
1 LCMCE - Laboratoire de Chimie Moléculaire et de Catalyse pour l'Energie (ex LCCEF)
NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M)
Abstract : An iron catalyst is shown for the first time to promote transfer hydrosilylation with silyl formates and utilized for the silylation of alcohols. Attractive features of this protocol include the use of an earth abundant transition metal catalyst, mild reaction conditions and the release of gases as the only by-products (H2 and CO2).
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Timothé Godou, Clément Chauvier, Pierre Thuéry, Thibault Cantat. Iron-Catalyzed Silylation of Alcohols by Transfer Hydrosilylation with Silyl Formates. SYNLETT, Georg Thieme Verlag, 2017, 28, pp.A-E. ⟨10.1055/s-0036-1591508⟩. ⟨cea-01621212⟩

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