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Journal articles
Silylation of O–H Bonds by Catalytic Dehydrogenative and Decarboxylative Coupling of Alcohols with Silyl Formates
Abstract : The silylation of O–H bonds is a useful methodology in organic synthesis and materials science. While this transformation is commonly achieved by reacting alcohols with reactive chlorosilanes or hydrosilanes, we show herein for the first time that silylformates HCO$_2$SiR$_3$ are efficient silylating agents for alcohols, in the presence of a ruthenium molecular catalyst.
Cited literature [9 references]
https://hal-cea.archives-ouvertes.fr/cea-01612948
Contributor : Serge Palacin Connect in order to contact the contributor
Submitted on : Monday, October 9, 2017 - 8:33:38 AM
Last modification on : Thursday, July 1, 2021 - 4:44:01 PM
Long-term archiving on: : Wednesday, January 10, 2018 - 12:33:20 PM
Contributor : Serge Palacin Connect in order to contact the contributor
Submitted on : Monday, October 9, 2017 - 8:33:38 AM
Last modification on : Thursday, July 1, 2021 - 4:44:01 PM
Long-term archiving on: : Wednesday, January 10, 2018 - 12:33:20 PM
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C7CC05212J_V0.pdf
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