Silylation of O–H Bonds by Catalytic Dehydrogenative and Decarboxylative Coupling of Alcohols with Silyl Formates - Archive ouverte HAL Access content directly
Journal Articles Chemical Communications Year : 2017

Silylation of O–H Bonds by Catalytic Dehydrogenative and Decarboxylative Coupling of Alcohols with Silyl Formates

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Abstract

The silylation of O–H bonds is a useful methodology in organic synthesis and materials science. While this transformation is commonly achieved by reacting alcohols with reactive chlorosilanes or hydrosilanes, we show herein for the first time that silylformates HCO$_2$SiR$_3$ are efficient silylating agents for alcohols, in the presence of a ruthenium molecular catalyst.
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cea-01612948 , version 1 (09-10-2017)

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Clément Chauvier, Timothé Godou, Thibault Cantat. Silylation of O–H Bonds by Catalytic Dehydrogenative and Decarboxylative Coupling of Alcohols with Silyl Formates. Chemical Communications, 2017, 53, pp.11697-11700. ⟨10.1039/C7CC05212J⟩. ⟨cea-01612948⟩
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