# Effect of Ionic Strength on the Bundling of Metal Oxide Imogolite Nanotubes

* Auteur correspondant
2 LIONS - Laboratoire Interdisciplinaire sur l'Organisation Nanométrique et Supramoléculaire
NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M)
Abstract : Significant developments have been proposed over the last decade in the synthesis of aluminosilicate and aluminogermanate imogolite-like nanotubes. But while liquid phase synthesis is well controlled, it is not the case for imogolite or imogolite-like nanotube arrangement in dry state. In particular, nanotubes are found to self-assemble in bundles of various sizes, which may impact the properties of the final product. Here, we investigate the effect of ionic strength on bundling of aluminogermanate single-walled imogolite nanotubes (Ge-SWINT) in aqueous suspensions and in the resulting powders after solvent evaporation. The nanotube arrangement as a function of salt concentration was studied by X-ray scattering experiments and simulations. In aqueous suspension, nanotubes bundling occurs only at high ionic strength (IS > 8 × 10$^{-2}$ mol.L$^{-1}$) while beyond this threshold, the increase of electrostatic repulsions induces a complete stabilization of individual nanotubes. After solvent evaporation, nanotube arrangement is shown to be dictated principally by the initial concentration of salt. Beyond an ionic strength of ~ 10$^{-3}$ mol.L$^{-1}$ in the starting suspension, all Ge-SWINT samples tend to form large bundles in powder, whose lattice parameter are independent of the initial salt concentrations. These experimental results clearly show that the positive surface charge of imogolite can be used to control nanotubes bundling by anion condensation.
Type de document :
Article dans une revue
Journal of Physical Chemistry C, American Chemical Society, 2017, 121, pp.21740-21749. 〈http://dx.doi.org/10.1021/acs.jpcc.7b07391〉. 〈10.1021/acs.jpcc.7b07391〉
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https://hal-cea.archives-ouvertes.fr/cea-01589860
Contributeur : Serge Palacin <>
Soumis le : mardi 19 septembre 2017 - 10:50:40
Dernière modification le : mercredi 21 mars 2018 - 18:57:54

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Erwan Paineau, Mohamed Amara, Geoffrey Monet, Véronique Peyre, Stéphan Rouzière, et al.. Effect of Ionic Strength on the Bundling of Metal Oxide Imogolite Nanotubes. Journal of Physical Chemistry C, American Chemical Society, 2017, 121, pp.21740-21749. 〈http://dx.doi.org/10.1021/acs.jpcc.7b07391〉. 〈10.1021/acs.jpcc.7b07391〉. 〈cea-01589860〉

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