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Recent advances in structural studies of heterometallic uranyl-containing coordination polymers and polynuclear closed species

Pierre Thuéry 1 Jack Harrowfield 2
1 LCMCE - Laboratoire de Chimie Moléculaire et de Catalyse pour l'Energie (ex LCCEF)
NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M)
2 ISIS - Institut de Science et d'ingénierie supramoléculaires
Abstract : AN OVERVIEW IS GIVEN OF RECENT STRUCTURAL STUDIES ON HETEROMETALLIC URANYL-CONTAINING SPECIES, WITH PARTICULAR EMPHASIS ON THOSE FORMED WITH CARBOXYLATE LIGANDS, SHOWING THE EFFECT OF THE ADDITIONAL METAL CATIONS AND ANCILLARY LIGANDS ON THE GEOMETRY AND TOPOLOGY OF THE ASSEMBLIES GENERATED. THESE EXAMPLES ILLUSTRATE THE SOPHISTICATION WHICH IS NOW POSSIBLE IN THE DESIGN AND SYNTHESIS OF BOTH URANYL CLUSTERS AND COORDINATION POLYMERS.
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https://hal-cea.archives-ouvertes.fr/cea-01588256
Contributor : Serge Palacin <>
Submitted on : Friday, September 15, 2017 - 1:54:31 PM
Last modification on : Monday, February 10, 2020 - 6:13:58 PM

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Pierre Thuéry, Jack Harrowfield. Recent advances in structural studies of heterometallic uranyl-containing coordination polymers and polynuclear closed species. Dalton Transactions, Royal Society of Chemistry, 2017, 46, pp.13660-13667. ⟨10.1039/C7DT03105J⟩. ⟨cea-01588256⟩

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