Abstract : A crystal structure determination of the Pb(II) coordination polymer [Pb(Mephen)(1,5-nds)(H2O)]n provides not only evidence of the common action of Pb(II) as a Lewis acid but also clear proof of its ability, in the solid state at least, to act as a Lewis base. This action as a base is attributed to the presence of a valence shell lone pair and its identification here is further evidence for the occasional but not universally detectable influence of the lone pair on the metal ion stereochemistry.
https://hal-cea.archives-ouvertes.fr/cea-01573207
Contributeur : Serge Palacin
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Soumis le : mardi 8 août 2017 - 17:59:19
Dernière modification le : vendredi 19 octobre 2018 - 11:46:41
