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Journal articles
Lead(II): Lewis acid and occasional base, as illustrated by its complex with 1,5-naphthalenedisulfonate and 5-methyl-1,10-phenanthroline
Abstract : A crystal structure determination of the Pb(II) coordination polymer [Pb(Mephen)(1,5-nds)(H2O)]n provides not only evidence of the common action of Pb(II) as a Lewis acid but also clear proof of its ability, in the solid state at least, to act as a Lewis base. This action as a base is attributed to the presence of a valence shell lone pair and its identification here is further evidence for the occasional but not universally detectable influence of the lone pair on the metal ion stereochemistry.
https://hal-cea.archives-ouvertes.fr/cea-01573207
Contributor : Serge Palacin Connect in order to contact the contributor
Submitted on : Tuesday, August 8, 2017 - 5:59:19 PM
Last modification on : Friday, January 7, 2022 - 3:53:50 AM
Contributor : Serge Palacin Connect in order to contact the contributor
Submitted on : Tuesday, August 8, 2017 - 5:59:19 PM
Last modification on : Friday, January 7, 2022 - 3:53:50 AM
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