Lead(II): Lewis acid and occasional base, as illustrated by its complex with 1,5-naphthalenedisulfonate and 5-methyl-1,10-phenanthroline

Jack Harrowfield 1 Pierre Thuéry 2
2 LCMCE - Laboratoire de Chimie Moléculaire et de Catalyse pour l'Energie (ex LCCEF)
NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M)
Abstract : A crystal structure determination of the Pb(II) coordination polymer [Pb(Mephen)(1,5-nds)(H2O)]n provides not only evidence of the common action of Pb(II) as a Lewis acid but also clear proof of its ability, in the solid state at least, to act as a Lewis base. This action as a base is attributed to the presence of a valence shell lone pair and its identification here is further evidence for the occasional but not universally detectable influence of the lone pair on the metal ion stereochemistry.
Type de document :
Article dans une revue
Dalton Transactions, Royal Society of Chemistry, 2017, 46, pp.11533-11536. 〈http://pubs.rsc.org/en/content/articlelanding/2017/dt/c7dt01975k#!divAbstract〉. 〈10.1039/C7DT01975K〉
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https://hal-cea.archives-ouvertes.fr/cea-01573207
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Soumis le : mardi 8 août 2017 - 17:59:19
Dernière modification le : jeudi 1 février 2018 - 01:29:21

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Jack Harrowfield, Pierre Thuéry. Lead(II): Lewis acid and occasional base, as illustrated by its complex with 1,5-naphthalenedisulfonate and 5-methyl-1,10-phenanthroline. Dalton Transactions, Royal Society of Chemistry, 2017, 46, pp.11533-11536. 〈http://pubs.rsc.org/en/content/articlelanding/2017/dt/c7dt01975k#!divAbstract〉. 〈10.1039/C7DT01975K〉. 〈cea-01573207〉

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