Alignment of Ge-imogolite nanotubes in isomalt with tunable inter-tube distances

Clément Levard (1) , Antoine Thill (2) , Astrid Avellan (1) , Cyprien Mauroy (1) , Vladimir Vidal (1) , Andrea P.C. Campos (3) , Armand Masion (1) , Jérôme Rose (1)

1 CEREGE - Centre européen de recherche et d'enseignement des géosciences de l'environnement
2 LIONS - Laboratoire Interdisciplinaire sur l'Organisation Nanométrique et Supramoléculaire
3 AMU CP2M - Centre Pluridisciplinaire de Microscopie Electronique et de Microanalyse

This study shows the almost perfect alignment of inorganic nanotubes (Ge-imogolite) within polyol filaments. Alignment was obtained by simply cooling a Ge-imogolite-polyol mixture under mechanical stress. Additionally, inter-tube distances in the plane normal to the filaments can be tuned by simply varying the weight fraction of imogolite in the starting solution. The ease of the alignment protocol will stimulate interest for testing new applications which require a good control of the pore density and morphology (periodicity, and high monodispersity of the pore size distribution).

Domains: Chemical Sciences; Material chemistry

Clément Levard, Antoine Thill, Astrid Avellan, Cyprien Mauroy, Vladimir Vidal, et al.. Alignment of Ge-imogolite nanotubes in isomalt with tunable inter-tube distances. RSC Advances, 2017, 7, pp.21323 - 21327. ⟨10.1002/bbpc.19961000952⟩. ⟨cea-01516469⟩