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Journal Articles Angewandte Chemie International Edition Year : 2017

Chemistry of the 5g elements. Relativistic calculations on hexafluorides

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Abstract

A Periodic System was proposed for the elements 1-172 by Pyykkö (Phys. Chem. Chem. Phys. 2011, 13, 161) on the basis of atomic and ionic calculations. In it, the elements 121-138 were nominally assigned to a 5g row. We now perform molecular, relativistic four-component DFT calculations and find that the hexafluorides of the elements 125-129 indeed enjoy occupied 5g states.
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cea-01515489 , version 1 (27-04-2017)

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Attribution - NonCommercial - CC BY 4.0

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Jean-Pierre Dognon, Pekka Pyykkö. Chemistry of the 5g elements. Relativistic calculations on hexafluorides. Angewandte Chemie International Edition, 2017, 56, pp.10132-10134. ⟨10.1002/anie.201701609⟩. ⟨cea-01515489⟩
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