A New, Simple and Versatile Strategy for the Synthesis of Short Segments of Zigzag-Type Carbon Nanotubes

Étienne André 1 Baptiste Boutonnet 1 Pauline Charles 1 Cyril Martini 1 Juan-Manuel Aguiar-Hualde 2 Sylvain Latil 2 Vincent Guérineau 3 Karim Hammad 3 Priyanka Ray 1 Régis Guillot 1 Vincent Huc 1
1 ICMMO - Institut de Chimie Moléculaire et des Matériaux d'Orsay
2 GMT - Groupe Modélisation et Théorie
SPEC - UMR3680 - Service de physique de l'état condensé, IRAMIS - Institut Rayonnement Matière de Saclay
3 ICSN - Institut de Chimie des Substances Naturelles
Abstract : Short segments of zigzag single-walled carbon nanotubes (SWCNTs) were obtained from a calixarene scaffold by using a completely new, simple and expedited strategy that allowed fine-tuning of their diameters. This new approach also allows for functionalised short segments of zigzag SWCNTs to be obtained; a prerequisite towards their lengthening. These new SWCNT short segments/calixarene composites show interesting behaviour in solution. DFT analysis of these new compounds also suggests interesting photophysical behaviour. Along with the synthesis of various SWCNTs segments, this approach also constitutes a powerful tool for the construction of new, radially oriented π systems.
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https://hal-cea.archives-ouvertes.fr/cea-01492975
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Submitted on : Monday, March 20, 2017 - 4:59:14 PM
Last modification on : Thursday, February 7, 2019 - 5:12:28 PM

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CEA | CNRS | DSM-IRAMIS | ICSN | IRAMIS-SPEC | INC-CNRS | UNIV-PARIS-SACLAY | CEA-DRF | CEA-UPSAY

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Étienne André, Baptiste Boutonnet, Pauline Charles, Cyril Martini, Juan-Manuel Aguiar-Hualde, et al.. A New, Simple and Versatile Strategy for the Synthesis of Short Segments of Zigzag-Type Carbon Nanotubes. Chemistry - A European Journal, Wiley-VCH Verlag, 2016, 22 (9), pp.3105 - 3114. ⟨10.1002/chem.201503693⟩. ⟨cea-01492975⟩

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