Synthesis of new dithia[3.3]parapara- and metapara-cyclophane based tectons: toward an universal surface-confined 2D/3D molecular binding motif

Abstract : A series of new paraphenylene-based 2D and 3D tectons has been designed for supramolecular self-assembly on both HOPG and Au. Several versatile chemical strategies have been developed to reach the target tectons, bearing either metaparacyclophane or paraparacyclophane cores, functionalized or not, allowing the obtention soon of more complex 3D tectons bearing functional unit such as chromophores. Moreover, preliminary STM results show that these compounds can successfully self-assemble both on HOPG and Au(111) substrates at liquid-solid interface, encouraging us in finding an universal surface-confined 2D/3D molecular binding motif. This feature combined with the preliminary results of the self-assembly on the plasmonic substrate Au(111) open-up opportunities in the field of Nanoscience.
Type de document :
Article dans une revue
Pure and Applied Chemistry, De Gruyter, 2016, 88 (10-11), pp.1005-1025. 〈10.1515/pac-2016-0818〉
Liste complète des métadonnées

Littérature citée [23 références]  Voir  Masquer  Télécharger

https://hal-cea.archives-ouvertes.fr/cea-01483832
Contributeur : Dominique Girard <>
Soumis le : mardi 7 mars 2017 - 13:17:56
Dernière modification le : mercredi 21 mars 2018 - 18:57:54
Document(s) archivé(s) le : jeudi 8 juin 2017 - 13:40:57

Fichier

Zaborova_2016_Synthesis_of_new...
Fichiers produits par l'(les) auteur(s)

Identifiants

Citation

Elena Zaborova, Alice Six, Hanane Amokrane, Fabrice Charra, Fabrice Mathevet, et al.. Synthesis of new dithia[3.3]parapara- and metapara-cyclophane based tectons: toward an universal surface-confined 2D/3D molecular binding motif. Pure and Applied Chemistry, De Gruyter, 2016, 88 (10-11), pp.1005-1025. 〈10.1515/pac-2016-0818〉. 〈cea-01483832〉

Partager

Métriques

Consultations de la notice

172

Téléchargements de fichiers

41