Skip to Main content Skip to Navigation
Journal articles

Localized intermolecular electronic coupling in two-dimensional self-assembled 3,4,9,10-perylenetetracarboxylic diimide nanoarchitectures

Jérémy Hieulle 1 Fabien Silly 1
1 LEPO - Laboratoire d'Electronique et nanoPhotonique Organique
SPEC - UMR3680 - Service de physique de l'état condensé, IRAMIS - Institut Rayonnement Matière de Saclay
Abstract : Tailoring the structural and electronic properties of perylene diimide derivative films is essential for developing next generation organic photovoltaic devices. Here we show that 3,4,9,10-perylenetetracarboxylic diimide (PTCDI) molecules self-assemble into a new two-dimensional structure after annealing. Scanning tunneling microscopy (STM) reveals strong localized inter-molecular electronic coupling at room temperature when molecules are arranged in a side-by-side packing.
Document type :
Journal articles
Complete list of metadatas

Cited literature [21 references]  Display  Hide  Download

https://hal-cea.archives-ouvertes.fr/cea-01481322
Contributor : Dominique Girard <>
Submitted on : Thursday, March 2, 2017 - 2:10:46 PM
Last modification on : Monday, February 10, 2020 - 6:13:46 PM
Long-term archiving on: : Wednesday, May 31, 2017 - 2:21:14 PM

File

c3tc30771a.pdf
Files produced by the author(s)

Identifiers

Collections

Citation

Jérémy Hieulle, Fabien Silly. Localized intermolecular electronic coupling in two-dimensional self-assembled 3,4,9,10-perylenetetracarboxylic diimide nanoarchitectures. Journal of Materials Chemistry C, Royal Society of Chemistry, 2013, 1 (30), pp.4536-4539. ⟨10.1039/c3tc30771a⟩. ⟨cea-01481322⟩

Share

Metrics

Record views

179

Files downloads

233