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An optimized alkyl chain-based binding motif for 2D self-assembly: a comprehensive crystallographic approach

David Bléger 1 Amandine Bocheux 2 David Kreher 1 Fabrice Mathevet 1 Andre-Jean Attias 1 Germain Metgé 2 Ludovic Douillard 2 Céline Fiorini-Debuisschert 2 Fabrice Charra 2
1 LCP - Chimie des polymères
IPCM - Institut Parisien de Chimie Moléculaire, UPMC - Université Pierre et Marie Curie - Paris 6, CNRS - Centre National de la Recherche Scientifique : UMR7610
2 SPEC - UMR3680 - Service de physique de l'état condensé
Abstract : Taking into account substrate crystallographic constraints, an over-arching molecular binding motif has been designed to allow trans-ferable self-assembling patterns on different substrates. This optimized clip demonstrates robust and equivalent self-assembled architectures on both highly oriented pyrolitic graphite (HOPG) and reconstructed Au(111) surfaces.
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David Bléger, Amandine Bocheux, David Kreher, Fabrice Mathevet, Andre-Jean Attias, et al.. An optimized alkyl chain-based binding motif for 2D self-assembly: a comprehensive crystallographic approach. Nanoscale, Royal Society of Chemistry, 2013, 5, pp.1452 - 1455. ⟨10.1039/c2nr33509c⟩. ⟨cea-01478816⟩

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