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Journal articles
Transfer Hydrosilylation. Silyl Formates as Surrogates of Hydrosilanes and Their Application in the Transfer Hydrosilylation of Aldehydes
Abstract : Silyl formates are investigated for the first time as surrogates of hydrosilanes. In the presence of a well-defined ruthenium catalyst, these reagents are shown to promote the chemoselective reduction of a variety of aldehydes by transfer hydrosilylation. Mechanistic investigations have shown that genuine hydrosilane species are avoided during catalysis. The mechanism involves a sequence of decarboxylation/insertion/ transmetallation steps.
Cited literature [38 references]
https://hal-cea.archives-ouvertes.fr/cea-01391214
Contributor : Serge Palacin Connect in order to contact the contributor
Submitted on : Monday, January 21, 2019 - 6:39:26 PM
Last modification on : Thursday, July 1, 2021 - 4:43:42 PM
Contributor : Serge Palacin Connect in order to contact the contributor
Submitted on : Monday, January 21, 2019 - 6:39:26 PM
Last modification on : Thursday, July 1, 2021 - 4:43:42 PM
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Anie.201607201.pdf
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