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Synthesis and self-assembly properties of fullerene/porphyrin-phthalocyanine and fullerene/bis-phthalocyanine triads

Khanh Hy Le Ho 1 Bruno Jousselme 1 Stéphane Campidelli 1
1 LICSEN - Laboratoire Innovation en Chimie des Surfaces et NanoSciences
NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M)
Abstract : In this work, we report on the synthesis and characterization of two fulleropyrrolidines bearing porphyrin/phthalocyanine and bis-phthalocyanine tweezers. The self-assembly properties in different solvents have been investigated by AFM and SEM. When deposited on surface from dichloromethane solutions, the fullerene derivatives formed aggregates of ca. 4–8 nm in height while hollow nanospheres with diameters of ca. 300–1000 nm are obtained from crystallization attempts.
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https://hal-cea.archives-ouvertes.fr/cea-01369408
Contributor : Serge Palacin <>
Submitted on : Wednesday, September 21, 2016 - 7:35:36 AM
Last modification on : Monday, February 10, 2020 - 6:13:58 PM

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CEA | CNRS | DSM-IRAMIS | PUBNIMBE | IRAMIS-NIMBE | CEA-UPSAY | INC-CNRS | CEA-DRF

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Khanh Hy Le Ho, Bruno Jousselme, Stéphane Campidelli. Synthesis and self-assembly properties of fullerene/porphyrin-phthalocyanine and fullerene/bis-phthalocyanine triads. Journal of Porphyrins and Phthalocyanines, World Scientific Publishing, 2016, 20, pp.1-6. ⟨10.1142/S1088424616500772⟩. ⟨cea-01369408⟩

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