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Journal articles
Tuning the Magnetic Anisotropy at a Molecule-Metal Interface
Abstract : We demonstrate that a C 60 overlayer enhances the perpendicular magnetic anisotropy of a Co thin film, inducing an inverse spin reorientation transition from in plane to out of plane. The driving force is the C 60 =Co interfacial magnetic anisotropy that we have measured quantitatively in situ as a function of the C 60 coverage. Comparison with state-of-the-art ab initio calculations show that this interfacial anisotropy mainly arises from the local hybridization between C 60 p z and Co d z 2 orbitals. By generalizing these arguments, we also demonstrate that the hybridization of C 60 with a Fe(110) surface decreases the perpendicular magnetic anisotropy. These results open the way to tailor the interfacial magnetic anisotropy in organic-material–ferromagnet systems.
Cited literature [14 references]
https://hal-cea.archives-ouvertes.fr/cea-01366478
Contributor : Dominique Girard <>
Submitted on : Wednesday, September 14, 2016 - 4:20:52 PM
Last modification on : Thursday, July 1, 2021 - 4:46:39 PM
Long-term archiving on: : Thursday, December 15, 2016 - 3:11:53 PM
Contributor : Dominique Girard <>
Submitted on : Wednesday, September 14, 2016 - 4:20:52 PM
Last modification on : Thursday, July 1, 2021 - 4:46:39 PM
Long-term archiving on: : Thursday, December 15, 2016 - 3:11:53 PM
File
PhysRevLett.114.247203.pdf
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