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Journal Articles Journal of the American Chemical Society Year : 2015

Beyond Entropy: Magnetic Forces Induce Formation of Quasicrystalline Structure in Binary Nanocrystal Superlattices

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Abstract

Here, it is shown that binary superlattices of Co/Ag nanocrystals with the same size, surface coating, differing by their type of crystallinity are governed by Co–Co magnetic interactions. By using 9 nm amorphous-phase Co nanocrystals and 4 nm polycrystalline Ag nanocrystals at 25 °C, triangle-shaped NaCl-type binary nanocrystal superlattices are produced driven by the entropic force, maximizing the packing density. By contrast, using ferromagnetic 9 nm single domain (hcp) Co nanocrystals instead of amorphous-phase Co, dodecagonal quasicrystalline order is obtained, together with less-packed phases such as the CoAg13 (NaZn13-type), CoAg (AuCu-type), and CoAg3 (AuCu3-type) structures. On increasing temperature to 65 °C, 9 nm hcp Co nanocrystals become superparamagnetic, and the system yields the CoAg3 (AuCu3-type) and CoAg2 (AlB2-type) structures, as observed with 9 nm amorphous Co nanocrystals. Furthermore, by decreasing the Co nanocrystal size from 9 to 7 nm, stable AlB2-type binary nanocrystal superlattices are produced, which remain independent of the crystallinity of Co nanocrystals with the superparamagnetic state.
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Dates and versions

cea-01365887 , version 1 (13-09-2016)

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Zhijie Yang, Jingjing Weig, Pierre Bonville. Beyond Entropy: Magnetic Forces Induce Formation of Quasicrystalline Structure in Binary Nanocrystal Superlattices. Journal of the American Chemical Society, 2015, 137 (13), pp.4487-4493. ⟨10.1021/jacs.5b00332⟩. ⟨cea-01365887⟩
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