A. Abdulagatov, Y. Yan, J. Cooper, Y. Zhang, Z. Gibbs et al., Atomic Layer Deposition on Copper for Water Corrosion Resistance, ACS Applied Materials & Interfaces, vol.3, issue.12, pp.4593-460110, 1021.
DOI : 10.1021/am2009579

E. Angelini, F. Fracassi, D. Agostino, R. Grassini, S. Rosalbino et al., PECVD of organosilicon thin films for corrosion protection of metals, Trends in electrochemistry and corrosion at the beginning of the 21st century, p.20, 2004.

E. Angelini, S. Grassini, G. Solorzano, G. Campos, D. Caro et al., Integrated approach to the characterization and conservation of artefacts of the Brazilian colonial period, Applied Physics A, vol.79, issue.4, pp.485-491, 2006.
DOI : 10.1007/s00339-006-3544-x

H. Antony, S. Peulon, L. Legrand, and A. Chaussé, Electrochemical synthesis of lepidocrocite thin films on gold substrate???EQCM, IRRAS, SEM and XRD study, Electrochimica Acta, vol.50, issue.4, pp.1015-1021, 2004.
DOI : 10.1016/j.electacta.2004.07.043

H. Antony, L. Legrand, L. Maréchal, S. Perrin, P. Dillmann et al., Study of lepidocrocite ??-FeOOH electrochemical reduction in neutral and slightly alkaline solutions at 25??C, Electrochimica Acta, vol.51, issue.4, pp.745-753, 2005.
DOI : 10.1016/j.electacta.2005.05.049

H. Antony, S. Perrin, P. Dillmann, L. Legrand, and A. Chaussé, Electrochemical study of indoor atmospheric corrosion layers formed on ancient iron artefacts, Electrochimica Acta, vol.52, issue.27, pp.7754-7759, 2007.
DOI : 10.1016/j.electacta.2007.04.029

URL : https://hal.archives-ouvertes.fr/hal-00159815

D. Arribet-deroin, Fondre le fer en gueuses au XVIe siècle. Le haut fourneau de Glinet en pays de Bray (Normandie), 2001.

M. Aucouturier, F. Mathis, D. Robcis, J. Castaing, J. Salomon et al., Intentional patina of metal archaeological artefacts: non-destructive investigation of Egyptian and Roman museum treasures, Corrosion Engineering, Science and Technology, vol.10, issue.5, pp.314-32110, 1179.
DOI : 10.1016/B978-0-7506-1611-9.50011-X

I. Balta, S. Pederzoli, E. Iacob, and M. Bersani, Dynamic secondary ion mass spectrometry and X-ray photoelectron spectroscopy on artistic bronze and copper artificial patinas, Applied Surface Science, vol.255, issue.12, pp.6378-6385, 2009.
DOI : 10.1016/j.apsusc.2009.02.020

T. Ba?e, Z. Bastl, V. Havránek, K. Lang, J. Bould et al., Carborane???thiol???silver interactions. A comparative study of the molecular protection of silver surfaces, Surface and Coatings Technology, vol.204, issue.16-17, pp.2639-2646, 2010.
DOI : 10.1016/j.surfcoat.2010.02.019

C. Bataillon, C. Musy, and M. Roy, Corrosion des surconteneurs de d??chets, cas d'un surconteneur en acier faiblement alli??, Le Journal de Physique IV, vol.11, issue.PR1, pp.267-274, 2001.
DOI : 10.1051/jp4:2001127

C. Bataillon, F. Bouchon, C. Chainais-hillairet, C. Desgranges, E. Hoarau et al., Corrosion modelling of iron based alloy in nuclear waste repository, Electrochimica Acta, vol.55, issue.15, pp.4451-4467, 2010.
DOI : 10.1016/j.electacta.2010.02.087

URL : https://hal.archives-ouvertes.fr/hal-00556950

M. Bernard and S. Joiret, Understanding corrosion of ancient metals for the conservation of cultural heritage, Electrochimica Acta, vol.54, issue.22, pp.5199-5205, 2009.
DOI : 10.1016/j.electacta.2009.01.036

M. Bouchar, E. Foy, D. Neff, and P. Dillmann, The complex corrosion system of a medieval iron rebar from the Bourges??? Cathedral. Characterization and reactivity studies, Corrosion Science, vol.76, pp.361-372, 2013.
DOI : 10.1016/j.corsci.2013.07.007

P. Carcia, R. Mclean, B. Sauer, and M. Reilly, Atomic Layer Deposition Ultra-Barriers for Electronic Applications???Strategies and Implementation, Journal of Nanoscience and Nanotechnology, vol.11, issue.9, pp.7994-7998, 2011.
DOI : 10.1166/jnn.2011.5075

E. Castro, J. Vilche, and A. Arvia, Iron dissolution and passivation in K2CO3-KHCO3 solutions. rotating ring disc electrode and XPS studies, Corrosion Science, vol.32, issue.1, pp.37-50, 1991.
DOI : 10.1016/0010-938X(91)90062-T

C. Chiavari, K. Rahmouni, H. Takenouti, S. Joiret, P. Vermaut et al., Composition and electrochemical properties of natural patinas of outdoor bronze monuments, Electrochimica Acta, vol.52, issue.27, pp.7760-7769, 2007.
DOI : 10.1016/j.electacta.2006.12.053

M. Corfield, Preventive conservation for archaeological sites, Studies in Conservation, vol.41, issue.sup1, pp.26-30, 1996.
DOI : 10.1016/B978-0-408-10668-9.50007-1

M. Corfield and J. Williams, Review of " Preservation of archaeological remains in situ (PARIS 4), pp.24-29, 2011.

R. Agostino, F. Fracassi, F. Pagostino, R. Fracassi, F. Palumbo et al., Protection of Silver-Based Alloys from Tarnishing by Means of Plasma-Enhanced Chemical Vapor Deposition, Plasma Processes and Polymers, vol.29, issue.2, pp.91-96, 1997.
DOI : 10.1002/ppap.200400031

C. Degrigny, Use of artificial metal coupons to test new protection systems on cultural heritage objects: manufacturing and validation, Corrosion Engineering, Science and Technology, vol.2, issue.5, pp.367-374, 2010.
DOI : 10.1149/1.2129607

B. Díaz, E. Härkönen, J. ?wiatowska, V. Maurice, A. Seyeux et al., Low-temperature atomic layer deposition of Al2O3 thin coatings for corrosion protection of steel: Surface and electrochemical analysis, Corrosion Science, vol.53, issue.6, pp.2168-2175, 2011.
DOI : 10.1016/j.corsci.2011.02.036

B. Díaz, J. ?wiatowska, V. Maurice, A. Seyeux, N. B. Härkönen et al., Electrochemical and time-of-flight secondary ion mass spectrometry analysis of ultra-thin metal oxide (Al2O3 and Ta2O5) coatings deposited by atomic layer deposition on stainless steel, Electrochimica Acta, vol.56, issue.28, pp.10516-10523, 2011.
DOI : 10.1016/j.electacta.2011.02.074

P. Dillmann, From Soissons to Beauvais : the use of iron in some French cathedrals The archaeometallurgy of iron?recent developments in archaeological and scientific research, pp.173-196, 2011.

P. Dillmann, D. Arribet-deroin, E. Vega, and P. Benoit, Early modern cast iron and iron at Glinet, pp.99-106, 2003.

P. Dillmann, F. Mazaudier, and S. Hoerle, Advances in understanding atmospheric corrosion of iron. I. Rust characterisation of ancient ferrous artefacts exposed to indoor atmospheric corrosion, Corrosion Science, vol.46, issue.6, pp.1401-1429, 2004.
DOI : 10.1016/j.corsci.2003.09.027

P. Dillmann, D. Watkinson, E. Angelini, A. Adriens, P. Oxford-dillmann et al., Archaeological analogues and corrosion prediction: from past to future. A review, Corrosion Engineering, Science and Technology, vol.52, issue.27, pp.567-576, 2013.
DOI : 10.1016/j.corsci.2010.09.052

URL : https://hal.archives-ouvertes.fr/hal-01157706

A. Duran, L. Herrera, M. De-haro, A. Justo, and J. Perez-rodriguez, Non-destructive analysis of cultural heritage artefacts from Andalusia, Spain, by X-ray diffraction with G??bel mirrors, Talanta, vol.76, issue.1, pp.183-188, 2008.
DOI : 10.1016/j.talanta.2008.02.025

F. Fracassi, R. Agostino, F. Palumbo, E. Angelini, S. Grassini et al., Application of plasma deposited organosilicon thin films for the corrosion protection of metals, Surface and Coatings Technology, vol.174, issue.175, pp.107-111, 2003.
DOI : 10.1016/S0257-8972(03)00422-5

P. Hadsund, The tin-mercury mirror: its manufacturing technique and deterioration processes, Stud Conserv, vol.38, pp.3-16, 1993.

J. Han, D. Young, H. Colijn, A. Tripathi, and S. Ne?i?, Corrosion Environments, Industrial & Engineering Chemistry Research, vol.48, issue.13, pp.6296-6302, 2009.
DOI : 10.1021/ie801819y

L. Herrera, A. Duran, M. Franquelo, A. Gonzales-elipe, J. Espinos et al., Abstract, Open Chemistry, vol.7, issue.1, pp.47-53, 2008.
DOI : 10.2478/s11532-008-0089-1

L. Herrera, A. Duran, M. Franquelo, M. De-haro, A. Erbez et al., Studies of deterioration of the tin???mercury alloy within ancient Spanish mirrors, Journal of Cultural Heritage, vol.9, pp.41-46, 2008.
DOI : 10.1016/j.culher.2008.06.007

L. Herrera, A. Justo, and J. Perez-rodriguez, Study of Nanocrystalline SnO<sub>2</sub> Particles Formed during the Corrosion Processes of Ancient Amalgam Mirrors, Journal of Nano Research, vol.8, pp.99-107, 2009.
DOI : 10.4028/www.scientific.net/JNanoR.8.99

A. Hiorns, &. Macmillan, L. Co, S. Hollner, F. Mirambet et al., Evaluation of new non-toxic corrosion inhibitors for conservation of iron artefacts, Corros Eng Sci Technol, vol.45, pp.362-36610, 1179.

R. Hughes, R. M. Ingo, G. , D. Caro, T. Riccucci et al., The colouring, bronzing and patination of metals. Crafts Council Large scale investigation of chemical composition, structure and corrosion mechanism of bronze archeological artefacts from Mediterranean basin, Appl Phys A-Mater Sci Process, vol.83, pp.513-520, 1982.

K. Kashima, S. Hara, H. Kishikawa, and H. Miyuki, Evaluation of Protective Ability of Rust Layers on Weathering Steels by Potential Measurement, Zairyo-to-Kankyo, vol.49, issue.1, pp.25-37, 2001.
DOI : 10.3323/jcorr1991.49.15

Y. Leon, M. Saheb, E. Drouet, D. Neff, E. Foy et al., Interfacial layer on archaeological mild steel corroded in carbonated anoxic environments studied with coupled micro and nano probes, Corrosion Science, vol.88, pp.23-35, 2014.
DOI : 10.1016/j.corsci.2014.07.005

URL : https://hal.archives-ouvertes.fr/hal-01157704

S. Leroy, L. Héritier, M. Delqué-kolic, E. Dumoulin, J. Moreau et al., Consolidation or initial design? Radiocarbon dating of ancient iron alloys sheds light on the reinforcements of French Gothic Cathedrals, Journal of Archaeological Science, vol.53, pp.190-201, 2015.
DOI : 10.1016/j.jas.2014.10.016

URL : https://hal.archives-ouvertes.fr/hal-01187777

M. Leskelä and M. Ritala, Atomic layer deposition (ALD): from precursors to thin film structures, Thin Solid Films, vol.409, issue.1, pp.138-14610, 2002.
DOI : 10.1016/S0040-6090(02)00117-7

A. Marquardt, E. Breitung, T. Drayman-weisser, G. Gates, and R. Phaneuf, Protecting silver cultural heritage objects with atomic layer deposited corrosion barriers, Heritage Science, vol.145, issue.204, pp.1-12, 2015.
DOI : 10.1186/s40494-015-0066-x

R. Matero, M. Ritala, M. Leskelä, T. Salo, J. Aromaa et al., Atomic layer deposited thin films for corrosion protection, Le Journal de Physique IV, vol.09, issue.PR8, pp.8-493, 1999.
DOI : 10.1051/jp4:1999862

H. Matthiesen, D. Gregory, P. Jensen, and B. Sørensen, Environmental Monitoring at Nydam, a Waterlogged Site with Weapon Sacrifices from the Danish Iron Age. I: A Comparison of Methods Used and Results from Undisturbed Conditions, Journal of Wetland Archaeology, vol.50, issue.1, pp.55-74, 2004.
DOI : 10.4319/lo.1974.19.5.0857

H. Matthiesen, E. Salomonsen, and B. Sørensen, The use of radiography and GIS to assess the deterioration of archaeological iron objects from a water logged environment, Journal of Archaeological Science, vol.31, issue.10, pp.1451-1461, 2004.
DOI : 10.1016/j.jas.2004.03.013

A. Michelin, E. Drouet, E. Foy, J. Dynes, D. Neff et al., Investigation at the nanometre scale on the corrosion mechanisms of archaeological ferrous artefacts by STXM, J. Anal. At. Spectrom., vol.139, issue.1, pp.59-66, 2013.
DOI : 10.1016/j.gca.2008.02.002

J. Monnier, P. Dillmann, L. Legrand, and I. Guillot, Corrosion of iron from heritage buildings: proposal for degradation indexes based on rust layer composition and electrochemical reactivity, Corrosion Engineering, Science and Technology, vol.52, issue.27, pp.375-380, 2010.
DOI : 10.1016/j.electacta.2009.01.036

J. Monnier, D. Neff, S. Réguer, P. Dillmann, L. Bellot-gurlet et al., A corrosion study of the ferrous medieval reinforcement of the Amiens cathedral. Phase characterisation and localisation by various microprobes techniques, Corrosion Science, vol.52, issue.3, pp.695-710, 2010.
DOI : 10.1016/j.corsci.2009.10.028

J. Monnier, I. Guillot, L. Legrand, and P. Dillmann, Reactivity studies of atmospheric corrosion of heritage iron artefacts (eds) Corrosion and conservation of cultural heritage metallic artefacts, pp.285-310, 2013.

J. Muller, G. Lorang, E. Leroy, B. Laik, and I. Guillot, Electrochemically synthesised bronze patina: characterisation and application to the cultural heritage, Corrosion Engineering, Science and Technology, vol.149, issue.3, pp.322-326, 2010.
DOI : 10.1021/ac052192s

J. Muller and B. Laïk, ??-CuSn bronzes in sulphate medium: Influence of the tin content on corrosion processes, Corrosion Science, vol.77, pp.46-51
DOI : 10.1016/j.corsci.2013.07.025

D. Neff, P. Dillmann, L. Bellot-gurlet, and G. Beranger, Corrosion of iron archaeological artefacts in soil: characterisation of the corrosion system, Corrosion Science, vol.47, issue.2, pp.515-535, 2005.
DOI : 10.1016/j.corsci.2004.05.029

L. Paussa, L. Guzman, E. Marin, N. Isomaki, and L. Fedrizzi, Protection of silver surfaces against tarnishing by means of alumina/titania-nanolayers, Surface and Coatings Technology, vol.206, issue.5, 2011.
DOI : 10.1016/j.surfcoat.2011.03.101

M. Pourbaix, Electrochemical corrosion and reduction. Corrosion and metal artifatcs : a dialogue between conservators and archaeologists, pp.1-16, 1977.

R. Puurunen, Surface chemistry of atomic layer deposition: A case study for the trimethylaluminum/water process, Journal of Applied Physics, vol.97, issue.12, 2005.
DOI : 10.1063/1.1940727

C. Rangel, I. Fonseca, and R. Leitão, Some aspects of the electrochemical behaviour of mild steel in carbonate/bicarbonate solutions, Electrochimica Acta, vol.31, issue.12, pp.1659-166210, 1986.
DOI : 10.1016/0013-4686(86)87089-X

L. Robbiola, J. Blengino, and C. Fiaud, Morphology and mechanisms of formation of natural patinas on archaeological Cu???Sn alloys, Corrosion Science, vol.40, issue.12, pp.2083-2111, 1998.
DOI : 10.1016/S0010-938X(98)00096-1

M. Saheb, M. Descostes, D. Neff, H. Matthiesen, A. Michelin et al., Iron corrosion in an anoxic soil: Comparison between thermodynamic modelling and ferrous archaeological artefacts characterised along with the local in situ geochemical conditions, Applied Geochemistry, vol.25, issue.12, pp.1937-1948, 2010.
DOI : 10.1016/j.apgeochem.2010.10.010

M. Saheb, D. Neff, J. Demory, E. Foy, and P. Dillmann, Characterisation of corrosion layers formed on ferrous archaeological artefacts buried in anoxic media, Corrosion Engineering, Science and Technology, vol.28, issue.4, pp.381-387, 2010.
DOI : 10.1038/246527a0

M. Schlegel, C. Bataillon, K. Benhamida, C. Blanc, D. Menut et al., Metal corrosion and argillite transformation at the water-saturated, high-temperature iron???clay interface: A microscopic-scale study, Applied Geochemistry, vol.23, issue.9, pp.2619-2633, 2008.
DOI : 10.1016/j.apgeochem.2008.05.019

M. Schlegel, C. Bataillon, F. Brucker, C. Blanc, D. Prêt et al., Corrosion of metal iron in contact with anoxic clay at 90??C: Characterization of the corrosion products after two years of interaction, Applied Geochemistry, vol.51, pp.1-14, 2014.
DOI : 10.1016/j.apgeochem.2014.09.002

URL : https://hal.archives-ouvertes.fr/hal-01157703

D. Scott and G. Eggert, Iron and steel in art: corrosion, colorants, conservation, 2009.

L. Selwyn, N. Binnie, J. Poitras, M. Laver, and D. Downham, Outdoor bronze statues: analysis of metal and surface samples, Stud Conserv, vol.41, pp.205-228, 1996.

Y. Shashoua, H. Matthiesen, G. Spoto, E. Ciliberto, G. Allen et al., Protection of iron and steel in large outdoor industrial heritage objects, Corrosion Engineering, Science and Technology, vol.45, issue.5, pp.357-361, 2000.
DOI : 10.1179/147842210X12710800383648

M. Stratmann, The investigation of the corrosion properties of metals, covered with adsorbed electrolyte layers???A new experimental technique, Corrosion Science, vol.27, issue.8, pp.869-872, 1987.
DOI : 10.1016/0010-938X(87)90043-6

M. Stratmann and H. Streckel, On the atmospheric corrosion of metals which are covered with thin electrolyte layers???II. Experimental results, Corrosion Science, vol.30, issue.6-7, pp.697-714, 1990.
DOI : 10.1016/0010-938X(90)90033-2

M. Stratmann, H. Streckel, K. Kim, and S. Crockett, On the atmospheric corrosion of metals which are covered with thin electrolyte layers-iii. the measurement of polarisation curves on metal surfaces which are covered by thin electrolyte layers, Corrosion Science, vol.30, issue.6-7, pp.715-734, 1990.
DOI : 10.1016/0010-938X(90)90034-3

C. Wang, B. Lu, J. Zuo, S. Zhang, S. Tan et al., Structural and elemental analysis on the nanocrystalline SnO2 in the surface of ancient Chinese black mirrors, Nanostructured Materials, vol.5, issue.4, pp.489-496, 1995.
DOI : 10.1016/0965-9773(95)00258-G