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Synergistic effects in ambiphilic phosphino-borane catalysts for the hydroboration of CO$_2$

Anis Tlili 1 Arnaud Voituriez 2 Angela Marinetti 2 Pierre Thuéry 1 Thibault Cantat 1
1 LCMCE - Laboratoire de Chimie Moléculaire et de Catalyse pour l'Energie (ex LCCEF)
NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M)
2 ICSN - Institut de Chimie des Substances Naturelles
Abstract : The benefit of combining both a Lewis acid and a Lewis base in a catalytic system has been established for the hydroboration of CO$_2$, using ferrocene-based phosphine, borane and phosphino-borane derivatives
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Anis Tlili, Arnaud Voituriez, Angela Marinetti, Pierre Thuéry, Thibault Cantat. Synergistic effects in ambiphilic phosphino-borane catalysts for the hydroboration of CO$_2$. Chemical Communications, Royal Society of Chemistry, 2016, 52, pp.7553-7555. ⟨10.1039/c6cc02809h⟩. ⟨cea-01329300⟩

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