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Journal articles
Multi-channel electronic and vibrational dynamics in polyatomic resonant high-order harmonic generation
A. Ferré
1
A. E. Boguslavskiy
2
M. Dagan
3
Valérie Blanchet
1
B. D. Bruner
3
F. Burgy
1
A. Camper
4
D. Descamps
1
B. Fabre
1
N. Fedorov
1
J. Gaudin
1
G. Geoffroy
1
J. Mikosch
2, 5
S. Patchkovskii
2, 5
S. Petit
1
T. Ruchon
4, 6
H. Soifer
3
David Staedter
7
I. Wilkinson
2
A. Stolow
2, 8
N. Dudovich
3
Y. Mairesse
1
6
ATTO - Attophysique
IRAMIS - Institut Rayonnement Matière de Saclay, LIDyl - Laboratoire Interactions, Dynamiques et Lasers (ex SPAM)
A. Ferré 1
Author
A. E. Boguslavskiy 2
Author
M. Dagan 3
Author
Valérie Blanchet 1
Author IdHAL : valerie-blanchet arXiv : https://arxiv.org/a/blanchet#2 ResearcherId : http://www.researcherid.com/rid/L-3677-2014 ORCID : https://orcid.org/0000-0002-6464-3879
B. Fabre 1
Author IdHAL : baptiste-fabre ORCID : https://orcid.org/0000-0001-9843-8139
N. Fedorov 1
Author
J. Gaudin 1
Author
G. Geoffroy 1
Author
N. Dudovich 3
Author
Y. Mairesse 1
Author
1
CELIA - Centre d'Etudes Lasers Intenses et Applications (351 cours de la libération 33405 Talence - France)
- CNRS - Centre National de la Recherche Scientifique : UMR5107 (France)
- CEA - Commissariat à l'énergie atomique et aux énergies alternatives : DAM/CESTA (Centre de Saclay Centre de Grenoble Centre de Cadarache etc - France)
- UB - Université de Bordeaux (35, place Pey Berland - 33076 Bordeaux - France)
2
NRC - National Research Council of Canada (1200 Montreal Road, Building M-58, Ottawa, Ontario K1A 0R6 - Canada)
3
Department of Physics of Complex System (Rehovot 76100, Israel - Israel)
- Weizmann Institute of Science [Rehovot, Israël] (234 Herzl Street, Rehovot 7610001 - Israel)
4
LIDyl - Laboratoire Interactions, Dynamiques et Lasers (ex SPAM) (LIDYL, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91190 Gif sur Yvette - France)
- Université Paris-Saclay (Espace Technologique, Bat. Discovery - RD 128 - 2e ét., 91190 Saint-Aubin - France)
- CEA - Commissariat à l'énergie atomique et aux énergies alternatives : DRF/IRAMIS (Centre de Saclay Centre de Grenoble Centre de Cadarache etc - France)
- CNRS - Centre National de la Recherche Scientifique : UMR9222 (France)
5
MBI - Max-Born-Institut für Nichtlineare Optik und Kurzzeitspektroskopie (Max-Born-Straße 2 A, 12489 Berlin - Germany)
6
ATTO - Attophysique (France)
- IRAMIS - Institut Rayonnement Matière de Saclay (91191 Gif-sur-Yvette, France - France)
- CEA - Commissariat à l'énergie atomique et aux énergies alternatives : DRF/IRAMIS (Centre de Saclay Centre de Grenoble Centre de Cadarache etc - France)
- Université Paris-Saclay (Espace Technologique, Bat. Discovery - RD 128 - 2e ét., 91190 Saint-Aubin - France)
- LIDyl - Laboratoire Interactions, Dynamiques et Lasers (ex SPAM) (LIDYL, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91190 Gif sur Yvette - France)
- Université Paris-Saclay (Espace Technologique, Bat. Discovery - RD 128 - 2e ét., 91190 Saint-Aubin - France)
- CEA - Commissariat à l'énergie atomique et aux énergies alternatives : DRF/IRAMIS (Centre de Saclay Centre de Grenoble Centre de Cadarache etc - France)
- CNRS - Centre National de la Recherche Scientifique : UMR9222 (France)
7
Femto (LCAR) (LCAR - IRSAMC
UMR 5589
Université Paul Sabatier - Bât. 3R1b4
118 route de Narbonne
31062 TOULOUSE CEDEX 09 - France)
- LCAR - Laboratoire Collisions Agrégats Réactivité (31062 Toulouse cedex 04 - France - France)
- IRSAMC - Institut de Recherche sur les Systèmes Atomiques et Moléculaires Complexes : UMR5589 (UPS - IRSAMC. - Bat. IIIr1-B4. - 118 route de Narbonne 31062 Toulouse cedex - France)
- INSA Toulouse - Institut National des Sciences Appliquées - Toulouse (135, avenue de Rangueil - 31077 Toulouse cedex 4 - France)
- UT3 - Université Toulouse III - Paul Sabatier (118 route de Narbonne - 31062 Toulouse - France)
- Université Fédérale Toulouse Midi-Pyrénées (41 Allée Jules Guesde, 31000 Toulouse - France)
- CNRS - Centre National de la Recherche Scientifique : FR2568 (France)
- IRSAMC - Institut de Recherche sur les Systèmes Atomiques et Moléculaires Complexes : UMR5589 (UPS - IRSAMC. - Bat. IIIr1-B4. - 118 route de Narbonne 31062 Toulouse cedex - France)
8
Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Ontario, Canada KIN 6N5 (Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Ontario, Canada KIN 6N5 - Canada)
- uOttawa - University of Ottawa [Ottawa] (75 Laurier Avenue East, Ottawa, ON K1N 6N5 - Canada)
Abstract : High-order harmonic generation in polyatomic molecules generally involves multiple channels of ionization. Their relative contribution can be strongly influenced by the presence of resonances, whose assignment remains a major challenge for high-harmonic spectroscopy. Here we present a multi-modal approach for the investigation of unaligned polyatomic molecules, using SF6 as an example. We combine methods from extreme-ultraviolet spectroscopy, above-threshold ionization and attosecond metrology. Fragment-resolved above-threshold ionization measurements reveal that strong-field ionization opens at least three channels. A shape resonance in one of them is found to dominate the signal in the 20–26 eV range. This resonance induces a phase jump in the harmonic emission, a switch in the polarization state and different dynamical responses to molecular vibrations. This study demonstrates a method for extending high-harmonic spectroscopy to polyatomic molecules, where complex attosecond dynamics are expected.
Document type :
Journal articles
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Complete list of metadatas
https://hal-cea.archives-ouvertes.fr/cea-01244391
Contributor : Caroline Lebe <>
Submitted on : Tuesday, December 15, 2015 - 4:37:46 PM
Last modification on : Thursday, October 15, 2020 - 2:42:03 PM
Contributor : Caroline Lebe <>
Submitted on : Tuesday, December 15, 2015 - 4:37:46 PM
Last modification on : Thursday, October 15, 2020 - 2:42:03 PM
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Identifiers
- HAL Id : cea-01244391, version 1
- DOI : 10.1038/ncomms6952
Collections
CEA | CNRS | CELIA | DSM-IRAMIS | IRAMIS-LIDYL | IRSAMC | LCAR_FEM | CEA-UPSAY | UNIV-PARIS-SACLAY | CEA-DRF | DAM | UNIV-TLSE3 | INSA-TOULOUSE | LCAR
Citation
A. Ferré, A. E. Boguslavskiy, M. Dagan, Valérie Blanchet, B. D. Bruner, et al.. Multi-channel electronic and vibrational dynamics in polyatomic resonant high-order harmonic generation. Nature Communications, Nature Publishing Group, 2015, 6, pp.5952. ⟨10.1038/ncomms6952⟩. ⟨cea-01244391⟩
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