Spatial variability of transport parameters in the Boom Clay, Applied Clay Science, vol.26, issue.1-4, pp.37-45, 2004. ,
DOI : 10.1016/j.clay.2003.09.015
Proton Activity Inside the Channels of Zeolite L, Chemistry - A European Journal, vol.39, issue.32, pp.8939-8952, 2007. ,
DOI : 10.1002/chem.200700569
Diffusion-driven transport in clayrock formations, Applied Geochemistry, vol.27, issue.2, pp.463-478, 2012. ,
DOI : 10.1016/j.apgeochem.2011.09.015
URL : https://hal.archives-ouvertes.fr/hal-00664227
Multicomponent Diffusion Modeling in Clay Systems with Application to the Diffusion of Tritium, Iodide, and Sodium in Opalinus Clay, Environmental Science & Technology, vol.41, issue.14, pp.5002-5007, 2007. ,
DOI : 10.1021/es0629256
Multicomponent diffusion of a suite of tracers (HTO, Cl, Br, I, Na, Sr, Cs) in a single sample of Opalinus Clay, Geochimica et Cosmochimica Acta, vol.74, issue.4, pp.1201-1219, 2010. ,
DOI : 10.1016/j.gca.2009.11.013
Analytical solutions for calculating the anion porosity and effective diffusion coefficients in illite, 2013. ,
The Hydrolysis of Cations, 1976. ,
A mechanistic description of Ni and Zn sorption on Na-montmorillonite Part I: Titration and sorption measurements, Journal of Contaminant Hydrology, vol.27, issue.3-4, pp.199-222, 1997. ,
DOI : 10.1016/S0169-7722(97)00008-9
Cation exchange capacity measurements on illite using the sodium and cesium isotope dilution technique: effects of the index cation, electrolyte concentration and competition: modeling, clays and clay minerals, vol.52, issue.4, pp.421-431, 2004. ,
DOI : 10.1346/CCMN.2004.0520403
Characterization of iodide retention on Callovo-Oxfordian argillites and its influence on iodide migration, Physics and Chemistry of the Earth, Parts A/B/C, vol.31, issue.10-14, pp.517-522, 2006. ,
DOI : 10.1016/j.pce.2006.04.015
URL : https://hal.archives-ouvertes.fr/hal-00159997
Characterization of sulphate sorption on Callovo-Oxfordian argillites by batch, column and through-diffusion experiments, Physics and Chemistry of the Earth, Parts A/B/C, vol.32, issue.8-14, pp.552-558, 2007. ,
DOI : 10.1016/j.pce.2006.01.010
URL : https://hal.archives-ouvertes.fr/hal-00276061
Geochemical and Biogeochemical Reaction Modeling, 2008. ,
DOI : 10.1017/CBO9780511619670
Basic geochemical data from water sampling (WS) experiments, Phases 1 and 2, 1998. ,
Modeling diffusion and adsorption in compacted bentonite: a critical review, Journal of Contaminant Hydrology, vol.61, issue.1-4, pp.293-302, 2003. ,
DOI : 10.1016/S0169-7722(02)00128-6
Tracer diffusion in compacted, water-saturated bentonite, Clays and Clay Minerals, vol.54, issue.3, pp.363-374, 2006. ,
DOI : 10.1346/CCMN.2006.0540307
A mechanistic description of Ni and Zn sorption on Na-montmorillonite Part II: modelling, Journal of Contaminant Hydrology, vol.27, issue.3-4, pp.223-248, 1997. ,
DOI : 10.1016/S0169-7722(97)00007-7
Modelling the sorption of Zn and Ni on Ca-montmorillonite, Geochimica et Cosmochimica Acta, vol.63, issue.3-4, pp.325-336, 1998. ,
DOI : 10.1016/S0016-7037(98)00281-6
A generalised sorption model for the concentration dependent uptake of caesium by argillaceous rocks, Journal of Contaminant Hydrology, vol.42, issue.2-4, pp.141-163, 2000. ,
DOI : 10.1016/S0169-7722(99)00094-7
Experimental and Modelling Investigations on Na-illite: Acid-Base Behaviour and the Sorption of Strontium, Nickel, Europium and Uranyl. PSI Bericht Nr, pp.5-7, 2005. ,
Modelling the sorption of Mn(II), Co(II), Ni(II), Zn(II), Cd(II), Eu(III), Am(III), Sn(IV), Th(IV), Np(V) and U(VI) on montmorillonite: Linear free energy relationships and estimates of surface binding constants for some selected heavy metals and actinides, Co(II), Ni(II) Eu(III), Am(III), Sn(IV) Th(IV), pp.875-892, 2005. ,
DOI : 10.1016/j.gca.2004.07.020
Sorption of Eu(III)/Cm(III) on Ca-montmorillonite and Na-illite. Part 2: Surface complexation modelling, Geochimica et Cosmochimica Acta, vol.69, issue.23, pp.5403-5412, 2005. ,
DOI : 10.1016/j.gca.2005.06.031
URL : https://hal.archives-ouvertes.fr/hal-00082169
Sorption modelling on illite Part I: Titration measurements and the sorption of Ni, Co, Eu and Sn, Geochimica et Cosmochimica Acta, vol.73, issue.4, pp.990-1003, 2009. ,
DOI : 10.1016/j.gca.2008.11.017
Sorption modelling on illite. Part II: Actinide sorption and linear free energy relationships, Geochimica et Cosmochimica Acta, vol.73, issue.4, pp.1004-1013, 2009. ,
DOI : 10.1016/j.gca.2008.11.016
Predictive sorption modelling of Ni(II), Co(II), Eu(IIII), Th(IV) and U(VI) on MX-80 bentonite and Opalinus Clay: A ???bottom-up??? approach, Applied Clay Science, vol.52, issue.1-2, pp.27-33, 2011. ,
DOI : 10.1016/j.clay.2011.01.022
MODELLING A FOOD MICROSTRUCTURE BY RANDOM SETS, Image Analysis & Stereology, vol.23, issue.1, pp.33-44, 2004. ,
DOI : 10.5566/ias.v23.p33-44
URL : https://hal.archives-ouvertes.fr/hal-00142174
Cesium and rubidium ion equilibriums in illite clay, The Journal of Physical Chemistry, vol.87, issue.7, pp.1213-1219, 1983. ,
DOI : 10.1021/j100230a024
Tritiated water retention and migration behaviour in Boom Clay: SFC1 level 5 report: First full Draft ? status, 2009. ,
Adsorption of Gases in Multimolecular Layers, Journal of the American Chemical Society, vol.60, issue.2, p.10, 1938. ,
DOI : 10.1021/ja01269a023
Up-Scaling of Molecular Diffusion Coefficients in Clays: A Two-Step Approach, The Journal of Physical Chemistry C, vol.115, issue.14, pp.6703-6714, 2011. ,
DOI : 10.1021/jp112325n
Zinc Adsorption on Clays Inferred from Atomistic Simulations and EXAFS Spectroscopy, Environmental Science & Technology, vol.46, issue.11, pp.5713-5719, 2012. ,
DOI : 10.1021/es204423k
Mercury porosimetry of hardened cement pastes, Cement and Concrete Research, vol.29, issue.6, pp.933-943, 1999. ,
DOI : 10.1016/S0008-8846(99)00083-6
The Mathematics of Diffusion, 1975. ,
The Conundrum of pH in Water Nanodroplets: Sensing pH in Reverse Micelle Water Pools, Accounts of Chemical Research, vol.45, issue.10, pp.1637-1645, 2012. ,
DOI : 10.1021/ar200269g
Structural evidence for the sorption of Ni(II) atoms on the edges of montmorillonite clay minerals: a polarized X-ray absorption fine structure study, Geochimica et Cosmochimica Acta, vol.67, issue.1, pp.1-15, 2003. ,
DOI : 10.1016/S0016-7037(02)01005-0
Surface complexation modeling in aqueous geochemistry, Chapitre 5 dans Mineral-water interface geochemistry, 1990. ,
Geochemistry of Boom Clay pore water at the Mol site, 2004. ,
Inverse modeling in the time domain for solving diffusion in a heterogeneous rock matrix, Geophysical Research Letters, vol.42, issue.2, p.1147, 2003. ,
DOI : 10.1029/2002GL016428
Modelling diffusion in a heterogeneous rock matrix with a time-domain Lagrangian method and an inversion procedure, Comptes Rendus Geoscience, vol.334, issue.13, pp.967-973, 2002. ,
DOI : 10.1016/S1631-0713(02)01835-7
New algorithms in 3D image analysis and their application to the measurement of a spatialized pore size distribution in soils, Physics and Chemistry of the Earth, Part A: Solid Earth and Geodesy, vol.24, issue.7, pp.639-644, 1999. ,
DOI : 10.1016/S1464-1895(99)00093-9
Definition of an equilibration protocol for batch experiments on Callovo-Oxfordian argillite, Physics and Chemistry of the Earth, Parts A/B/C, vol.29, issue.1, pp.79-90, 2004. ,
DOI : 10.1016/j.pce.2003.11.010
Diffusion of anionic species in Callovo-Oxfordian argillites and Oxfordian limestones (Meuse/Haute???Marne, France), Applied Geochemistry, vol.23, issue.4, pp.655-677, 2008. ,
DOI : 10.1016/j.apgeochem.2007.11.003
Standard thermodynamic properties and heat capacity equations of rare earth hydroxides:, Comparison of thermochemical and solubility data, pp.327-347, 1998. ,
DOI : 10.1016/S0009-2541(98)00088-6
Modélisation prédictive de la migration des anions par description de la microstructure de la roche : application à l'argilite du Callovo-Oxfordian, 2009. ,
Evolution of microstructures and of macroscopic properties of some clays during experimental compaction, Marine and Petroleum Geology, vol.15, issue.2, pp.109-128, 1998. ,
DOI : 10.1016/S0264-8172(97)00062-7
A micromechanics-based nonlocal constitutive equation and estimates of representative volume element size for elastic composites, Journal of the Mechanics and Physics of Solids, vol.44, issue.4, pp.497-524, 1996. ,
DOI : 10.1016/0022-5096(96)00007-5
Surface complexation modeling, Hydrous ferric oxide, 1990. ,
Influence of redox conditions on iodide migration through a deep clay formation (Toarcian argillaceous rock, Tournemire, France), Applied Geochemistry, vol.27, issue.12, pp.2453-2462, 2012. ,
DOI : 10.1016/j.apgeochem.2012.09.003
URL : https://hal.archives-ouvertes.fr/hal-00738179
Diffusion of HTO, 36Cl-, and 125I-in Opalinus Clay samples from Mont Terri: Effect of confining pressure. Data Handbook for Clay Minerals and Others Non-metallic Minerals, 1979. ,
Etude minéralogique et géochimique de la série sédimentaire oligocène du Vela, B. Soc. Fr. Mineral CR, vol.86, pp.315-354, 1963. ,
15 years of in situ cement???argillite interaction from Tournemire URL: Characterisation of the multi-scale spatial heterogeneities of pore space evolution, Applied Geochemistry, vol.26, issue.12, pp.2159-2171, 2011. ,
DOI : 10.1016/j.apgeochem.2011.07.013
URL : https://hal.archives-ouvertes.fr/hal-00665328
In-situ interaction of cement paste and shotcrete with claystones in a deep disposal context, -situ Interaction of Cement Paste and Shotcrete with Claystones in a Deep Disposal Context, pp.314-356, 2012. ,
DOI : 10.2475/03.2012.03
URL : https://hal.archives-ouvertes.fr/hal-00832358
Numerical and statistical estimates of the representative volume element of elastoplastic random composites, European Journal of Mechanics - A/Solids, vol.33, pp.31-38, 2012. ,
DOI : 10.1016/j.euromechsol.2011.07.010
ANDRA underground research laboratory: interpretation of the mineralogical and geochemical data acquired in the Callovian???Oxfordian formation by investigative drilling, Physics and Chemistry of the Earth, Parts A/B/C, vol.29, issue.1, pp.55-77, 2004. ,
DOI : 10.1016/j.pce.2003.11.006
URL : https://hal.archives-ouvertes.fr/hal-00664755
How Mobile Are Sorbed Cations in Clays and Clay Rocks?, Environmental Science & Technology, vol.45, issue.4, pp.1443-1449, 2011. ,
DOI : 10.1021/es1027794
Sr in Montmorillonite:?? Evidence of Interlayer Diffusion Being the Dominant Pathway at High Compaction, Environmental Science & Technology, vol.41, issue.2, pp.478-485, 2007. ,
DOI : 10.1021/es061908d
Comparative study of HTO, 22 Na + and 36 Cl-36 -in compacted kaolinite, illite and montmorillonite, Geochim. Cosmochim. Acta, vol.74, 1999. ,
Comparative study of tracer diffusion of HTO, 22 Na + and 36 Cl -in compacted kaolinite, illite and montmorillonite, Geochim. Cosmochim. Acta, vol.74, 1999. ,
Diffusion of moderately and strongly sorbing radionuclides in compacted illite, 2012: Deliverable 2-1 EC CatClay project ,
in Compacted Montmorillonite, Environmental Science & Technology, vol.47, issue.20, pp.11522-11527, 2013. ,
DOI : 10.1021/es401968c
Local gradients as a possible source for biased results in through-diffusion experiments. A practical and theoretical approach using 85 Sr 2+ diffusion in compacted illite as a case study ,
Sorption of Cs, Am(III), Cm, Ac(III) Tc(IV) Th, Zr and U(IV) on MX80 bentonite: an experimental approach to asses model uncertainty, pp.627-636, 2006. ,
URL : https://hal.archives-ouvertes.fr/in2p3-00117310
Modelling the adsorption of Cd(II), Cu(II), Ni(II), Pb(II), and Zn(II) onto Fithian illite, Cu(II), Ni(II), pp.317-325, 2007. ,
DOI : 10.1016/j.jcis.2006.11.022
Update on the Chemical Thermodynamics of Uranium, Neptunium, Plutonium, Americium and Technetium, Chemical Thermodynamics, vol.5, 2003. ,
AFM and low-pressure argon adsorption analysis of geometrical properties of phyllosilicates, Journal of Colloid and Interface Science, vol.296, issue.2, pp.614-623, 2006. ,
DOI : 10.1016/j.jcis.2005.09.028
URL : https://hal.archives-ouvertes.fr/hal-00086907
The influence of compaction on the diffusion of non-sorbed species in Boom Clay. Radioactive Waste Management and the Nuclear Fuel Cycle, pp.1-14, 1991. ,
Boom Clay mineralogy -qualitative and quantitative aspects. Status 2012, 2012. ,
Diffusion and sorption on hardened cement pastes ? experiments and modelling results, pp.99-105, 1999. ,
Effects of sorption competition on caesium diffusion through compacted argillaceous rock, Geochimica et Cosmochimica Acta, vol.73, issue.9, pp.2441-2456, 2009. ,
DOI : 10.1016/j.gca.2009.01.028
The effect of elliptical pores on mercury porosimetry results, Powder Technology, vol.38, issue.2, pp.177-180, 1984. ,
DOI : 10.1016/0032-5910(84)80047-9
Complexation of Europium(III) by Aqueous Orthosilicic Acid, Radiochimica Acta, vol.72, issue.3, pp.143-150, 1996. ,
DOI : 10.1524/ract.1996.72.3.143
Diffusion of U(VI) in Opalinus Clay: Influence of temperature and humic acid, Geochimica et Cosmochimica Acta, vol.109, pp.74-89, 2013. ,
DOI : 10.1016/j.gca.2013.01.027
Measuring Free Metal Ion Concentrations in Multicomponent Solutions Using the Donnan Membrane Technique, Analytical Chemistry, vol.79, issue.4, pp.1555-1563, 2007. ,
DOI : 10.1021/ac0615403
On the application of focused ion beam nanotomography in characterizing the 3D pore space geometry of Opalinus clay, Physics and Chemistry of the Earth, Parts A/B/C, vol.36, issue.17-18, pp.1539-1544, 2011. ,
DOI : 10.1016/j.pce.2011.07.010
Characterization of multi-scale microstructural features in Opalinus Clay, Microporous and Mesoporous Materials, vol.170, pp.83-94, 2013. ,
DOI : 10.1016/j.micromeso.2012.11.029
Luminescence study on determination of the hydration number of Cm(III), Journal of Alloys and Compounds, vol.213, issue.214, pp.313-317, 1994. ,
DOI : 10.1016/0925-8388(94)90921-0
Determination of the Hydration Number of Cm(III) in Various Aqueous Solutions, Radiochimica Acta, vol.72, issue.2, pp.61-64, 1996. ,
DOI : 10.1524/ract.1996.72.2.61
Activation Energy for Diffusion of Cesium in Compacted Sodium Montmorillonite, Journal of Nuclear Science and Technology, vol.24, issue.6, pp.522-524, 1996. ,
DOI : 10.1021/la00047a025
Effect of Dry Density on Activation Energy for Diffusion of Strontium in Compacted Sodium Montmorillonite, MRS Proceedings, vol.71, pp.893-900, 1997. ,
DOI : 10.1016/0956-053X(93)90058-5
Self-diffusion of sodium ions in compacted sodium montmorillonite, Nucl. Technol, vol.121, pp.63-69, 1998. ,
A Model for Metal Adsorption on Montmorillonite, Journal of Colloid and Interface Science, vol.210, issue.1, pp.43-54, 1999. ,
DOI : 10.1006/jcis.1998.5947
Diffusion of ions in sea water and in deep-sea sediments, Geochim. Cosmochim. Acta, vol.38, pp.703-74, 1974. ,
Yttrium and Rare Earth Element Complexation by Chloride Ions at 25°C, Journal of Solution Chemistry, vol.30, issue.9, pp.837-845, 2001. ,
DOI : 10.1023/A:1012292417793
The Influence of Ionic Strength on Yttrium and Rare Earth Element Complexation by Fluoride Ions in NaClO4, NaNO3 and NaCl Solutions at 25?????C, Journal of Solution Chemistry, vol.8, issue.6, pp.673-689, 2007. ,
DOI : 10.1007/s10953-007-9141-6
Stability of metal uncharged ligand complexes in ion exchangers. Part 2.- The Copper+Ethylenediamine Complex in Montmorillonite and Sulphoric Acid Resin, J. Chem. Soc. Farad, vol.74, pp.1-182, 1978. ,
Stability of metal uncharged ligand complexes in ion exchangers. Part 4.???Hydration effects and stability changes of copper???ethylenediamine complexes in montmorillonite, Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, vol.75, issue.0, pp.1-513, 1979. ,
DOI : 10.1039/f19797500513
Highly Selective Ion Exchange in Clay Minerals and Zeolites, Geochemical processes at mineral surfaces, pp.254-295, 1986. ,
DOI : 10.1021/bk-1987-0323.ch013
Retention of Cs in Boom Clay: Comparison of data from batch sorption tests and diffusion experiments on intact clay cores, Physics and Chemistry of the Earth, Parts A/B/C, vol.33, pp.149-155, 2008. ,
DOI : 10.1016/j.pce.2008.10.002
Cs, Sr and Am retention on argillaceous host rocks: comparison of data from batch sorption tests and diffuison experiments, 2009. ,
Strontium retention and migration behaviour in Boom Clay, 2012. ,
INFLUENCE OF METAL SPECIATION IN LANDFILL LEACHATES ON KAOLINITE SORPTION, Water Research, vol.32, issue.3, pp.882-890, 1998. ,
DOI : 10.1016/S0043-1354(97)00288-1
Donnan Membrane Approach: From Equilibrium to Dynamic Speciation, Environmental Science & Technology, vol.40, issue.17, pp.5496-5501, 2006. ,
DOI : 10.1021/es060608t
URL : https://hal.archives-ouvertes.fr/cea-00278074
Microscopic simulation of structure and dynamics of water and counterions in a monohydrated montmorillonite, The Journal of Chemical Physics, vol.117, issue.7, pp.3454-3463, 2002. ,
DOI : 10.1063/1.1493186
URL : https://hal.archives-ouvertes.fr/hal-00160601
Cesium sorption and diffusion in Bure mudrock samples, Applied Clay Science, vol.29, issue.3-4, pp.172-186, 2005. ,
DOI : 10.1016/j.clay.2004.12.008
Diffusion coefficients of alkaline cations in Bure mudrock, Physics and Chemistry of the Earth, Parts A/B/C, vol.32, issue.1-7, pp.453-462, 2007. ,
DOI : 10.1016/j.pce.2006.04.035
Europium migration in argillaceous rocks: On the use of micro Laser-Induced Breakdown Spectroscopy (microLIBS) as a microanalysis tool, Materials Research Society Symposium Proceedings 932, pp.913-918, 2006. ,
on MX-80 Bentonite; Effect of Compaction Using the ???Capillary Method???, Environmental Science & Technology, vol.40, issue.15, pp.4672-4679, 2006. ,
DOI : 10.1021/es052483i
URL : https://hal.archives-ouvertes.fr/in2p3-00097254
Diffusion of 22 Na+, 85 Sr2+, 134 Cs+ and 57 Co2+ in bentonite clay compacted to different densities: experiments and modeling, Radiochimica Acta, vol.90, pp.753-760, 2002. ,
A set of semi-analytical solutions for parameter estimation in diffusion cell experiments, 1998. ,
Diffusion of Chloride and Uranium in Compacted Sodium Bentonite, MRS Proceedings, vol.127, pp.743-748, 1989. ,
DOI : 10.1557/PROC-127-743
A comprehensive thermodynamic model for the solubility and hydrolysis of Nd(III) and Am(III) in dilute to concentrated NaCl, MgCl 2 and CaCl 2 solutions. Book of Abstracts of the Migration'07 conference, p.60, 2007. ,
A Quantitative Model for Ion Diffusion in Compacted Bentonite, Radiochimica Acta, vol.82, issue.s1, pp.437-443, 1998. ,
DOI : 10.1524/ract.1998.82.special-issue.437
An integrated sorption???diffusion model for the calculation of consistent distribution and diffusion coefficients in compacted bentonite, Journal of Contaminant Hydrology, vol.47, issue.2-4, pp.283-296, 2001. ,
DOI : 10.1016/S0169-7722(00)00157-1
Description of input and examples for PHREEQC version 3 -A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations, A43, 497 p, 2013. ,
Opalinus Clay Experimental Water: A1 Type, Version 980318, 1998. ,
Buffers for pH and Metal Ion Control, 1974. ,
DOI : 10.1007/978-94-009-5874-6
Critical evaluation of thermodynamics of complex formation of metal ions in aqueous solutions. V. hydrolysis and hydroxo-complexes of Co2+ at 298.15 K, Hydrometallurgy, vol.48, issue.2, pp.153-169, 1998. ,
DOI : 10.1016/S0304-386X(97)00078-9
Experimental and modelling studies of caesium sorption on illite, Geochimica et Cosmochimica Acta, vol.63, issue.19-20, pp.3217-3227, 1999. ,
DOI : 10.1016/S0016-7037(99)00246-X
Experimental studies of Cs, Sr, Ni and Eu sorption on Na-illite and the modelling of Cs sorption. PSI Bericht Nr, pp.99-105, 1999. ,
Nouvelles méthodes quantitatives de cartographie de la minéralogie et de la porosité dans les matériaux argileux: application aux bentonites compactées des barrières ouvragées, 2003. ,
Porosity distribution in a clay gouge by image processing of 14C-PolyMethylMethAcrylate (14C-PMMA) autoradiographs:, Applied Clay Science, vol.27, issue.1-2, pp.107-118, 2004. ,
DOI : 10.1016/j.clay.2004.03.005
A new method for quantitative petrography based on image processing of chemical element maps: Part II. Semi-quantitative porosity maps superimposed on mineral maps, American Mineralogist, vol.95, issue.10, pp.1389-1398, 2010. ,
DOI : 10.2138/am.2010.3433
Sorption of Eu(III)/Cm(III) on Ca-montmorillonite and Na-illite. Part 1: Batch sorption and time-resolved laser fluorescence spectroscopy experiments, Geochimica et Cosmochimica Acta, vol.69, issue.23, pp.5393-5402, 2005. ,
DOI : 10.1016/j.gca.2005.06.030
URL : https://hal.archives-ouvertes.fr/hal-00082169
Sorption of heavy metals and radionuclides on zeolites and clays, NATO, Adv. Sci. I E-App, vol.362, pp.353-363, 1999. ,
Utilisation du chlorure de cobaltihexamine pour la détermination simultanée de la capacité d'échange et des bases échangeables dans les sols, Sciences du sol, vol.4, pp.269-275, 1976. ,
Rapport ANR SIMISOL (Tâche 6.2) Caractérisations multi-échelles de l'illite recompactée à partir d, 2011. ,
Caractérisations multi-échelles de l'illite re-compactée à partir d'observations au Microscope Electronique à Transmission, Rapport ANR SIMISOL, 2012. ,
Effects of mineral distribution at mesoscopic scale on solute diffusion in a clay-rich rock: Example of the Callovo-Oxfordian mudstone, Water Resour. Res, vol.48, p.5554, 2012. ,
URL : https://hal.archives-ouvertes.fr/hal-00827642
A multiscale approach to ion diffusion in clays: Building a two-state diffusion???reaction scheme from microscopic dynamics, Journal of Colloid and Interface Science, vol.309, issue.2, pp.289-295, 2007. ,
DOI : 10.1016/j.jcis.2007.01.090
URL : https://hal.archives-ouvertes.fr/hal-00168697
Dispersion of charged tracers in charged porous media, EPL (Europhysics Letters), vol.83, issue.3, p.34004, 2008. ,
DOI : 10.1209/0295-5075/83/34004
URL : https://hal.archives-ouvertes.fr/hal-00369645
Coarse-grained simulations of charge, current and flow in heterogeneous media. Faraday discuss, pp.223-243, 2010. ,
URL : https://hal.archives-ouvertes.fr/hal-00531704
An Imaging Method for the Porosity of Sedimentary Rocks: Adjustment of the PMMA Method--Example of a Characterization of a Calcareous Shale, Journal of Sedimentary Research, vol.72, issue.6, pp.937-943, 2002. ,
DOI : 10.1306/053002720937
Mapping and Quantifying the Clay Aggregate Microporosity in Medium- to Coarse-Grained Sandstones Using the 14C-PMMA Method, Journal of Sedimentary Research, vol.79, issue.8, pp.584-592, 2009. ,
DOI : 10.2110/jsr.2009.063
Effect of Dry Density on Diffusion of Some Radionuclides in Compacted Sodium Bentonite, Journal of Nuclear Science and Technology, vol.15, issue.4, pp.873-882, 1992. ,
DOI : 10.1080/18811248.1992.9731607
New Experimental Approach for Studying Diffusion through an Intact and Unsaturated Medium: A Case Study with Callovo-Oxfordian Argillite, Environmental Science & Technology, vol.44, issue.10, pp.3698-3704, 2010. ,
DOI : 10.1021/es903738t
Mobility of Cesium through the Callovo-Oxfordian Claystones under Partially Saturated Conditions. Sci Techno, pp.2633-2641, 2012. ,
How mobile is iodide in the Callovo?Oxfordian claystones underexperimental conditions close to the in situ ones? Hydrol, pp.142-143, 2012. ,
Mobility of zinc through the Callovo-Oxfordian Earth Plane, Sci, vol.7, pp.774-777, 2013. ,
Sorption of Metal Ions on Clay Minerals, Journal of Colloid and Interface Science, vol.220, issue.2, pp.392-405, 1999. ,
DOI : 10.1006/jcis.1999.6538
Sorption of Metal Ions on Clay Minerals, Journal of Colloid and Interface Science, vol.215, issue.1, pp.140-158, 1999. ,
DOI : 10.1006/jcis.1999.6253
Level Set Methods and Fast Marching Methods, 1999. ,
Laboratory diffusion testing for waste disposal ??? A review, Journal of Contaminant Hydrology, vol.7, issue.3, pp.177-217, 1991. ,
DOI : 10.1016/0169-7722(91)90028-Y
Competitive Fe(II)???Zn(II) Uptake on a Synthetic Montmorillonite, Environmental Science & Technology, vol.48, issue.1, pp.190-198, 2014. ,
DOI : 10.1021/es402783r
A selected thermodynamic database for REE to be used in HLNW performance assessment exercises, 1995. ,
Structure of water adsorbed on smectites, Chemical Reviews, vol.82, issue.6, pp.553-573, 1982. ,
DOI : 10.1021/cr00052a001
A ligand exchange model for the adsorption of inorganic and organic ligands at hydrous oxide interfaces, Croat. Chem. Acta, vol.53, pp.291-312, 1980. ,
Modelling Zn(II) sorption onto clayey sediments using a multi-site ion-exchange model, Applied Geochemistry, vol.24, issue.10, pp.24-1852, 2009. ,
DOI : 10.1016/j.apgeochem.2009.06.006
URL : https://hal.archives-ouvertes.fr/hal-00450629
Polymerization study of o-Si(OH)4 and complexation with Am(III), Eu(III) and Cm(III), Inorganica Chimica Acta, vol.360, issue.12, pp.3705-3711, 2007. ,
DOI : 10.1016/j.ica.2007.04.051
Migration of the Actinides Thorium, Protactinium, Uranium, Neptunium, Plutonium and Americium in Clay, Radiochimica Acta, vol.39, issue.2, pp.105-112, 1986. ,
DOI : 10.1524/ract.1986.39.2.105
Modelling approaches for anion-exclusion in compacted Na-bentonite, Geochimica et Cosmochimica Acta, vol.75, issue.13, pp.3698-3710, 2011. ,
DOI : 10.1016/j.gca.2011.04.001
URL : https://hal.archives-ouvertes.fr/hal-00597084
Modeling specific pH dependent sorption of divalent metals on montmorillonite surfaces. A review of pitfalls, recent achievements and current challenges, American Journal of Science, vol.313, issue.5, pp.395-451, 2013. ,
DOI : 10.2475/05.2013.01
URL : https://hal.archives-ouvertes.fr/hal-01027680
Analysis of diffusion in macroporous media in terms of a porosity, a tortuosity and a constrictivity factor, International Journal of Heat and Mass Transfer, vol.17, issue.9, pp.1093-1103, 1974. ,
DOI : 10.1016/0017-9310(74)90190-2
Diffusion of sorbing tracers in compacted clay, 2014. ,
Diffusion of HTO, 36Cl??? and 125I??? in Opalinus Clay samples from Mont Terri, Journal of Contaminant Hydrology, vol.61, issue.1-4, pp.73-83, 2003. ,
DOI : 10.1016/S0169-7722(02)00114-6
Effect of confining pressure on the diffusion of HTO, 36Cl??? and 125I??? in a layered argillaceous rock (Opalinus Clay): diffusion perpendicular to the fabric, Applied Geochemistry, vol.18, issue.10, pp.1653-1662, 2003. ,
DOI : 10.1016/S0883-2927(03)00047-7
Diffusion and retention of sodium and strontium in Opalinus clay: Comparison of sorption data from diffusion and batch sorption measurements, and geochemical calculations, Applied Geochemistry, vol.20, issue.12, pp.2351-2363, 2005. ,
DOI : 10.1016/j.apgeochem.2005.08.008
A high-resolution abrasive method for determining diffusion profiles of sorbing radionuclides in dense argillaceous rocks, Applied Radiation and Isotopes, vol.63, issue.1, pp.11-21, 2005. ,
DOI : 10.1016/j.apradiso.2005.02.001
Anion exclusion effects in compacted bentonites: Towards a better understanding of anion diffusion, Applied Geochemistry, vol.22, issue.11, pp.2536-2552, 2007. ,
DOI : 10.1016/j.apgeochem.2007.07.008
The sorption behaviour of caesium on Opalinus Clay: A comparison between intact and crushed material, Applied Geochemistry, vol.24, issue.5, pp.999-1004, 2009. ,
DOI : 10.1016/j.apgeochem.2009.03.003
Effective diffusion coefficients and porosity values for argillaceous rocks and bentonite: measured and estimated values for the provisional safety analyes for SGT-E2, 2013. ,
A modified version of the combined in-diffusion/abrasive peeling technique for measuring diffusion of strongly sorbing radionuclides in argillaceous rocks: A test study on the diffusion of caesium in Opalinus Clay, Applied Radiation and Isotopes, vol.90, pp.197-202, 2014. ,
DOI : 10.1016/j.apradiso.2014.04.009
Impact of different confluent fluid stream viscosities on interconnected porous static mixer device, Chem. Eng. Sci, vol.72, pp.172-178, 2012. ,
Contribution of Adsorbed Cations to Diffusion in Clay-Water Systems1, Soil Science Society of America Journal, vol.30, issue.1, pp.17-22, 1966. ,
DOI : 10.2136/sssaj1966.03615995003000010013x
Watersheds in digital spaces: an efficient algorithm based on immersion simulations, IEEE Transactions on Pattern Analysis and Machine Intelligence, vol.13, issue.6, pp.583-598, 1991. ,
DOI : 10.1109/34.87344
Interface Chemistry of Nanostructured Materials: Ion Adsorption on Mesoporous Alumina, Journal of Colloid and Interface Science, vol.254, issue.1, pp.23-30, 2002. ,
DOI : 10.1006/jcis.2002.8571
Effect of humic acid on the sorption of Cm(III) onto gamma-Al2O3 studied by the time-resolved laser fluorescence spectroscopy, Radiochim. Acta, vol.92, pp.691-695, 2004. ,
A thermochemical data base for phenomenological and safety assessment studies for disposal of radioactive waste in Belgium ? Data compilation strategy, 2011. ,
The Dynamics of Capillary Flow, Physical Review, vol.17, issue.3, pp.273-283, 1921. ,
DOI : 10.1103/PhysRev.17.273
Diffusion of HTO, Br???, I???, Cs+, 85Sr2+ and 60Co2+ in a clay formation: Results and modelling from an in situ experiment in Opalinus Clay, Applied Geochemistry, vol.23, issue.4, pp.678-691, 2008. ,
DOI : 10.1016/j.apgeochem.2007.11.004
The use of variograms in remote sensing: II. Real digital images, Remote Sensing of Environment, vol.25, issue.3, pp.349-379, 1988. ,
DOI : 10.1016/0034-4257(88)90109-5
Neptunium(V) Sorption and Diffusion in Opalinus Clay, Environmental Science & Technology, vol.43, issue.17, pp.6567-6571, 2009. ,
DOI : 10.1021/es9008568
Multiscale structures to describe porous media .1. Theoretical background and invasion by fluids. Transport Porous Med, pp.51-73, 1997. ,