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Journal articles
Isolation of the CH3˙ rotor in a thermally stable inert matrix: first characterization of the gradual transition from classical to quantum behaviour at low temperatures
Abstract : Matrix isolation is a method which plays a key role in isolating and characterizing highly reactive molecular
radicals. However, the isolation matrices, usually composed of noble gases or small diamagnetic molecules,
are stable only at very low temperatures, as they begin to desegregate even above a few tens of Kelvin.
Here we report on the successful isolation of CH3
radicals in the cages of a nearly inert clathrate–SiO2
matrix. This host is found to exhibit a comparable inertness with respect to that of most conventional
noble gas matrices but it is characterized by a peculiar thermal stability. The latter property is related to the
covalent nature of the host material and gives the opportunity to study the confined radicals from a few
degrees of Kelvin up to at least room temperature. Thanks to this advantage we were able to explore with
continuity for the first time the CH3
rotor properties by electron paramagnetic resonance spectroscopy,
starting from the quantum rotations which are observable only at the lowest temperatures (T E 4 K), going
through the gradual transition to the classical motion (4 K o T o 30 K), and ending with the properties of
the fully classical rotor (T 4 30 K). The method of isolation presented here is found to be very effective
and promising, as it is expected to be applicable to a large variety of different molecular radicals.
https://hal-cea.archives-ouvertes.fr/cea-01120972
Contributor : Boizot Bruno Connect in order to contact the contributor
Submitted on : Friday, February 27, 2015 - 10:09:05 AM
Last modification on : Friday, March 5, 2021 - 3:07:12 PM
Contributor : Boizot Bruno Connect in order to contact the contributor
Submitted on : Friday, February 27, 2015 - 10:09:05 AM
Last modification on : Friday, March 5, 2021 - 3:07:12 PM