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Synthesis of 2-D polymer from semi-amphiphilic Langmuir-Blodgett films

Abstract : Semi-amphiphilic monolayers formed via adsorption of tetraethynylpyridinium porphyrins to a dihexadecyl phosphate monolayer are allowed to react with ammoniacal silver nitrate or ammoniacal cuprous chloride, in order to form two-dimensional polymolecular species in which silver diacetylide groups or diacetylenic bonds are expected to link adjacent coplanar macrocycles. Evidences are given for the formation of these ultrathin two-dimensional networks.
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Submitted on : Thursday, August 21, 2014 - 3:46:09 PM
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Florence Porteu, Serge Palacin, Annie Ruaudel-Teixier, André Barraud. Synthesis of 2-D polymer from semi-amphiphilic Langmuir-Blodgett films. Macromolecular Symposia, Wiley-VCH Verlag, 1991, 46, pp.37-45. ⟨10.1002/masy.19910460107⟩. ⟨cea-01057157⟩



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