Synthesis of 2-D polymer from semi-amphiphilic Langmuir-Blodgett films - Archive ouverte HAL Access content directly
Journal Articles Macromolecular Symposia Year : 1991

Synthesis of 2-D polymer from semi-amphiphilic Langmuir-Blodgett films

Abstract

Semi-amphiphilic monolayers formed via adsorption of tetraethynylpyridinium porphyrins to a dihexadecyl phosphate monolayer are allowed to react with ammoniacal silver nitrate or ammoniacal cuprous chloride, in order to form two-dimensional polymolecular species in which silver diacetylide groups or diacetylenic bonds are expected to link adjacent coplanar macrocycles. Evidences are given for the formation of these ultrathin two-dimensional networks.

Dates and versions

cea-01057157 , version 1 (21-08-2014)

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Florence Porteu, Serge Palacin, Annie Ruaudel-Teixier, André Barraud. Synthesis of 2-D polymer from semi-amphiphilic Langmuir-Blodgett films. Macromolecular Symposia, 1991, 46, pp.37-45. ⟨10.1002/masy.19910460107⟩. ⟨cea-01057157⟩
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