Comparison of two means of attachment of an organometallic acid on gold surfaces by combining X-ray photoelectron spectroscopy and IR reflection spectroscopy

Chloé Chavigny 1 Franck Le Bideau 1 Claire-Marie Pradier 1 Serge Palacin 2 Pierre Brossier 3 Gérard Jaouen 1
1 Laboratoire Charles Friedel
2 LCSI - Laboratoire de Chimie des Surfaces et Interfaces
3 LIMA - Laboratoire Interactions Muqueuses Agents Transmissibles
Abstract : Two methods of immobilization of the butyric 4-oxocyclopentadienylmanganese tricarbonyl acid I on gold surface are presented: either through the assembly of a disulfide derived from the acid, or by coupling on a cystamine monolayer; the efficiency of these two ways are evaluated by IR reflection spectroscopy and X-ray photoelectron spectroscopy.
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Chloé Chavigny, Franck Le Bideau, Claire-Marie Pradier, Serge Palacin, Pierre Brossier, et al.. Comparison of two means of attachment of an organometallic acid on gold surfaces by combining X-ray photoelectron spectroscopy and IR reflection spectroscopy. Chemical Communications, Royal Society of Chemistry, 1998, 16, pp.1727-1728. ⟨10.1039/A802551G⟩. ⟨cea-01057052⟩

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