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Journal articles
Direct comparison of the electronic coupling efficiency of Sulfur and Selenium anchoring groups for molecules adsorbed onto gold electrodes
Abstract : We performed air and ultra-high vacuum scanning tunneling microscopy experiments in order to compare the electronic coupling provided by S and by Se used as alligator clips for bisthiol- and biselenol-terthiophene molecules adsorbed onto gold. The molecules were inserted in a dodecanethiol self-assembled monolayer. Their apparent height above the dodecanethiol matrix was used as a measure of the electronic coupling strength corresponding to S and Se, respectively. We show that the insertion behaviors of the two molecules are qualitatively the same, and that Se provides systematically a better coupling link than S whatever the tunneling conditions
https://hal-cea.archives-ouvertes.fr/cea-01056952
Contributor : Serge Palacin Connect in order to contact the contributor
Submitted on : Thursday, August 21, 2014 - 8:40:37 AM
Last modification on : Thursday, December 16, 2021 - 3:56:54 AM
Contributor : Serge Palacin Connect in order to contact the contributor
Submitted on : Thursday, August 21, 2014 - 8:40:37 AM
Last modification on : Thursday, December 16, 2021 - 3:56:54 AM
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