Tetrathiafulvalene-based podands bearing one or two thiol functions : Immobilization as self-assembled monolayers or polymer films, and recognition properties.

Joël Lyskawa 1, 2 Maitena Ocafrain 2 Gaelle Trippé 2 Franck Le Derf 2 Marc Sallé 2 Pascal Viel 1 Serge Palacin 1
1 LCSI - Laboratoire de Chimie des Surfaces et Interfaces
2 CIMMA - Laboratoire de Chimie, Ingénierie Moléculaire et Matériaux d'Angers
Abstract : The synthesis of various thiol and dithiol derivatives of a tetrathiafulvalene-based receptor is presented, as well as their immobilization on gold as self-assembled monolayers (SAMs). The formation of films incorporating TTF units is also shown by electrooxidation of TTF-dithiol derivatives. The ability of the monolayers to electrochemically recognize Pb2+ is demonstrated
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https://hal-cea.archives-ouvertes.fr/cea-01056940
Contributor : Serge Palacin <>
Submitted on : Thursday, August 21, 2014 - 8:05:38 AM
Last modification on : Saturday, May 11, 2019 - 1:21:09 AM

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Joël Lyskawa, Maitena Ocafrain, Gaelle Trippé, Franck Le Derf, Marc Sallé, et al.. Tetrathiafulvalene-based podands bearing one or two thiol functions : Immobilization as self-assembled monolayers or polymer films, and recognition properties.. Tetrahedron, Elsevier, 2006, 62, pp.4419-4425. ⟨10.1016/j.tet.2006.02.054⟩. ⟨cea-01056940⟩

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