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Orientation of Mn12 molecular nanomagnets in self-assembled monolayers

Abstract : The oriented grafting of the Mn12-carboxylate molecular nanomagnets has been achieved on semi-conducting flat Si(100) functionalized surfaces due to the bonding selectivity between axial and equatorial carboxylate groups present in the coordination sphere of the Mn12 complexes.
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https://hal-cea.archives-ouvertes.fr/cea-01022845
Contributor : Serge Palacin <>
Submitted on : Friday, July 11, 2014 - 8:21:12 AM
Last modification on : Wednesday, September 16, 2020 - 5:09:04 PM

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B. Fleury, V. Huc, Laure Catala, Pascale Jégou, Laurent Baraton, et al.. Orientation of Mn12 molecular nanomagnets in self-assembled monolayers. CrystEngComm, Royal Society of Chemistry, 2009, 11, pp.2192-2197. ⟨10.1039/b908525d⟩. ⟨cea-01022845⟩

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