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Journal articles
A low-cost strategy for $^{43}$Ca solid-state NMR spectroscopy
Abstract : Calcium-43 is a notoriously insensitive probe for nuclear magnetic resonance (NMR) due to its low natural abundance and small magnetic moment. Up until today, the few performed $^{43}$Ca solid-state NMR studies used either highly expensive $^{43}$Ca-enriched samples, or time consuming experiments on bulk natural abundance samples. We introduce the application of a magic-angle spinning coil (MACS) detector for a low-cost approach to $^{43}$Ca NMR spectroscopy of solid materials with high detection sensitivity. We demonstrate 1D and 2D $^{43}$Ca NMR spectra of a 1 mg $^{43}$Ca-enriched sample. The sample cost is about 150 €. The effect of off-resonance MACS is also presented here.
Cited literature [31 references]
https://hal-cea.archives-ouvertes.fr/cea-00854020
Contributor : Bruno Savelli Connect in order to contact the contributor
Submitted on : Tuesday, September 29, 2020 - 10:21:35 AM
Last modification on : Friday, March 5, 2021 - 3:10:13 PM
Long-term archiving on: : Wednesday, December 30, 2020 - 6:15:08 PM
Contributor : Bruno Savelli Connect in order to contact the contributor
Submitted on : Tuesday, September 29, 2020 - 10:21:35 AM
Last modification on : Friday, March 5, 2021 - 3:10:13 PM
Long-term archiving on: : Wednesday, December 30, 2020 - 6:15:08 PM
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