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Compact Hydrogen-Bonded Self-Assembly of Ni(II)−Salen Derivative Investigated Using Scanning Tunneling Microscopy

Abstract : The self-assembly of a Ni(II)−salen-derived complex bearing benzoate groups is investigated using scanning tunneling microscopy (STM) at the solid/liquid interface. STM reveals that the molecules form a two-dimensional nanoarchitecture of close-packed hydrogen-bonded chains on graphite surface. Favorable salen chain-shaped complementarity and molecular dipolar interactions appear to be at the origin of the compact molecular chain-packing.
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Marta Viciano-Chumillas, Jérémy Hieulle, Fabien Silly, Talal Mallah. Compact Hydrogen-Bonded Self-Assembly of Ni(II)−Salen Derivative Investigated Using Scanning Tunneling Microscopy. Journal of Physical Chemistry C, American Chemical Society, 2012, 116, pp.23404. ⟨10.1021/jp307168k⟩. ⟨cea-00838063⟩

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