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Two-Dimensional 1,3,5-Tris(4-carboxyphenyl)benzene Self-Assembly at the 1-Phenyloctane/Graphite Interface Revisited

Abstract : Two-dimensional (2D) self-assembly of star-shaped 1,3,5-tris(4-carboxyphenyl)benzene molecules is investigated. Scanning tunneling microscopy reveals that this molecule can form three hydrogen-bonded networks at the 1-phenyloctane/graphite interface. One of these structures is close-packed and the two other ones are porous structures, with hexagonal and rectangular cavities. The network with rectangular cavities appears to be the most stable structure.
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Fabien Silly. Two-Dimensional 1,3,5-Tris(4-carboxyphenyl)benzene Self-Assembly at the 1-Phenyloctane/Graphite Interface Revisited. Journal of Physical Chemistry C, American Chemical Society, 2012, 116, pp.10029. ⟨10.1021/jp300678m⟩. ⟨cea-00838043⟩

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