Abstract : Two-dimensional (2D) self-assembly of star-shaped 1,3,5-tris(4-carboxyphenyl)benzene molecules is investigated. Scanning tunneling microscopy reveals that this molecule can form three hydrogen-bonded networks at the 1-phenyloctane/graphite interface. One of these structures is close-packed and the two other ones are porous structures, with hexagonal and rectangular cavities. The network with rectangular cavities appears to be the most stable structure.
https://hal-cea.archives-ouvertes.fr/cea-00838043 Contributor : Fabien SillyConnect in order to contact the contributor Submitted on : Monday, June 24, 2013 - 4:12:28 PM Last modification on : Friday, March 5, 2021 - 3:10:15 PM Long-term archiving on: : Wednesday, September 25, 2013 - 4:11:03 AM
Fabien Silly. Two-Dimensional 1,3,5-Tris(4-carboxyphenyl)benzene Self-Assembly at the 1-Phenyloctane/Graphite Interface Revisited. Journal of Physical Chemistry C, American Chemical Society, 2012, 116, pp.10029. ⟨10.1021/jp300678m⟩. ⟨cea-00838043⟩